Akbari, A and Eftekhari Sis, B and Naderahmadian, A (2019) Silver and copper nanoparticles stabilized on ionic liquids-functionalized polyhedral oligomeric silsesquioxane (POSS): Highly active and recyclable hybrid catalysts. Polyhedron, 171. pp. 228-236.
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Abstract
Two novel heterogeneous hybrid catalysts were successfully synthesized using octa-aminopropyl poly- hedral oligomeric silsesquioxane hydrochloride salt (OA-POSS) and ionic liquids, followed by immobiliza- tion of Cu and Ag nanoparticles. The obtained hybrid catalysts, Cu@POSS-ILs and Ag@POSS-ILs, were characterized using FT-IR, SEM, EDX, TEM, XRD and TGA. Catalytic studies demonstrated that Cu@POSS-ILs was an excellent catalyst for click reaction in aqueous medium. Furthermore, Ag@POSS- ILs was also exhibited to be an active catalyst for 4-nitrophenol (4-NP) reduction. Simple preparation and easy catalysts recovery and recyclability of Cu@POSS-ILs and Ag@POSS-ILs for at least 3 and 6 runs, respectively, without loss of catalytic activity could be considered as important advantageous from cat- alytic application point of view.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Polyhedral oligomeric silsesquioxane nanoparticles Ionic liquids Metal nanoparticles Click reaction 4-Nitrophenol reduction |
| Subjects: | R Medicine > R Medicine (General) |
| Depositing User: | Unnamed user with email gholipour.s@umsu.ac.ir |
| Date Deposited: | 25 Jan 2020 08:16 |
| Last Modified: | 25 Jan 2020 08:16 |
| URI: | http://eprints.umsu.ac.ir/id/eprint/5808 |
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